Graphitic nanofibres from electrospun solutions of PAN in dimethylsulphoxide

TL;DR

This study presents a new low-toxicity method for synthesizing sub-60 nm graphitic nanofibres from electrospun polyacrylonitrile in DMSO, with detailed structural characterization after high-temperature heat treatment.

Contribution

It introduces a novel solution-based process for producing GNFs with controlled morphology and structure, including the effects of surfactants and oxidation steps.

Findings

GNFs have entangled micro-fibril structures with up to 40 graphene layers.

Heat treatment up to 3000°C enhances graphitisation without significant differences due to oxidation.

Oxidised GNFs retain more mass after high-temperature processing.

Abstract

Homogenous graphitic nanofibres (GNFs) have been synthesised by heat treatment of electrospun polyacrylonitrile in dimethylsulphoxide, offering a new solution route of low toxicity to manufacture sub-60 nm diameter GNFs. Fibre beading resulting from the spinning of low-concentration polymer solutions can be reduced with the addition of surfactant or sodium chloride. Characterisation techniques including X-ray diffraction, scanning- and transmission electron microscopy have been used to quantify the effect of the graphitisation process, by heat treatment up to 3000 deg. C, on the weight, diameter and structural morphology of the nanofibres. The GNFs have an entangled micro-fibril structure with graphitic ordering of up to 40 graphene layers after treatment at 3000 deg. C. There is little difference in the degree of graphitisation of GNFs prepared with a 250 deg. C oxidation step compared with those prepared without, but oxidised GNFs retain more of their original mass after heating under argon flow.