Cold gas as an ice diagnostic toward low mass protostars

TL;DR

This study explores an indirect method to diagnose ice composition in low-mass protostars by analyzing gas-phase molecules that originate from ice, using non-thermal desorption as a key process, with observations supporting the potential of this approach.

Contribution

It introduces an observational technique linking gas and ice abundances via non-thermal desorption, providing a new way to study ice chemistry in star-forming regions.

Findings

Gas to ice ratio of ~10^-4 matches model predictions.

Most gas-phase molecules are quiescent, not affected by thermal processes.

Tentative correlation between ice and gas phase abundances.

Abstract

Up to 90% of the chemical reactions during star formation occurs on ice surfaces, probably including the formation of complex organics. Only the most abundant ice species are however observed directly by infrared spectroscopy. This study aims to develop an indirect observational method of ices based on non-thermal ice desorption in the colder part of protostellar envelopes. For that purpose the IRAM 30m telescope was employed to observe two molecules that can be detected both in the gas and the ice, CH3 OH and HNCO, toward 4 low mass embedded protostars. Their respective gas-phase column densities are determined using rotational diagrams. The relationship between ice and gas phase abundances is subsequently determined. The observed gas and ice abundances span several orders of magnitude. Most of the CH3OH and HNCO gas along the lines of sight is inferred to be quiescent from the measured line widths and the derived excitation temperatures, and hence not affected by thermal desorption close to the protostar or in outflow shocks. The measured gas to ice ratio of ~10-4 agrees well with model predictions for non-thermal desorption under cold envelope conditions and there is a tentative correlation between ice and gas phase abundances. This indicates that non-thermal desorption products can serve as a signature of the ice composition. A larger sample is however necessary to provide a conclusive proof of concept.