Spin Dynamics in the Magnetoelectric Effect LiCoPO$_4$ Compound

TL;DR

This study investigates the spin dynamics of LiCoPO$_4$ using inelastic neutron scattering, revealing the importance of single-ion anisotropy and an anomalous low-energy excitation potentially linked to its magnetoelectric properties.

Contribution

The paper provides the first detailed analysis of spin excitations in LiCoPO$_4$, highlighting the role of single-ion anisotropy in its magnetic behavior.

Findings

Weak dispersion in magnetic excitation spectra

Single-ion anisotropy is as significant as exchange coupling

Detection of an anomalous low-energy excitation

Abstract

Inelastic neutron scattering (INS) experiments were performed to investigate the spin dynamics in magnetoelectric effect (ME) LiCoPO$_4$ single crystals. Weak dispersion was detected in the magnetic excitation spectra along the three principal crystallographic axes measured around the (0 1 0) magnetic reflection. Analysis of the data using linear spin-wave theory indicate that single-ion anisotropy in LiCoPO$_4$ is as important as the strongest nearest-neighbor exchange coupling. Our results suggest that Co$^{2+}$ single-ion anisotropy plays an important role in the spin dynamics of LiCoPO$_4$ and must be taken into account in understanding its physical properties. High resolution INS measurements reveal an anomalous low energy excitation that we hypothesize may be related to the magnetoelectric effect of LiCoPO$_4$.