Slow imbalance relaxation and thermoelectric transport in graphene

TL;DR

This paper investigates how slow carrier imbalance relaxation affects the thermal conductivity and thermoelectric power in monolayer graphene within the hydrodynamic regime, highlighting the role of sample length and contacts.

Contribution

It introduces a model accounting for slow imbalance relaxation and contact effects, revealing size-dependent thermoelectric behavior in graphene.

Findings

Thermoelectric response depends on the ratio of sample length to an intrinsic length scale l_Q.

For short samples, TC and TEP approach zero imbalance limits.

For long samples, TC and TEP reach intrinsic values characteristic of infinite imbalance relaxation.

Abstract

We compute the electronic component of the thermal conductivity (TC) and the thermoelectric power (TEP) of monolayer graphene, within the hydrodynamic regime, taking into account the slow rate of carrier population imbalance relaxation. Interband electron-hole generation and recombination processes are inefficient due to the non-decaying nature of the relativistic energy spectrum. As a result, a population imbalance of the conduction and valence bands is generically induced upon the application of a thermal gradient. We show that the thermoelectric response of a graphene monolayer depends upon the ratio of the sample length to an intrinsic length scale l_Q, set by the imbalance relaxation rate. At the same time, we incorporate the crucial influence of the metallic contacts required for the thermopower measurement (under open circuit boundary conditions), since carrier exchange with the contacts also relaxes the imbalance. These effects are especially pronounced for clean graphene, where the thermoelectric transport is limited exclusively by intercarrier collisions. For specimens shorter than l_Q, the population imbalance extends throughout the sample; the TC and TEP asymptote toward their zero imbalance relaxation limits. In the opposite limit of a graphene slab longer than l_Q, at non-zero doping the TC and TEP approach intrinsic values characteristic of the infinite imbalance relaxation limit. Samples of intermediate (long) length in the doped (undoped) case are predicted to exhibit an inhomogeneous temperature profile, whilst the TC and TEP grow linearly with the system size. In all cases except for the shortest devices, we develop a picture of bulk electron and hole number currents that flow between thermally conductive leads, where steady-state recombination and generation processes relax the accumulating imbalance.