Modal abundances of CAIs: Implications for bulk chondrite element abundances and fractionations

TL;DR

This study compiles CAI modal abundances in various chondrites, revealing their distribution, correlation with Al excess, and implications for chondrite formation and element fractionation.

Contribution

It provides a comprehensive list of CAI modal abundances across chondrites and analyzes their impact on bulk element compositions and thermal history.

Findings

CAIs are Poisson distributed and small-area studies may underestimate their abundance.

Excess Al in carbonaceous chondrites correlates with CAI abundance, indicating CAIs delivered Al.

Most CAIs are minor components, with diverse size distributions suggesting multiple origins.

Abstract

Modal abundances of Ca,Al-rich inclusions (CAIs) are poorly known and reported data scatter across large ranges. We combine reported CAI modal abundances and our own set, and present a complete list of CAI modal abundances in carbonaceous chondrites. This includes (in area%): CV: 2.98, CM: 1.21, Acfer 094: 1.12, CO: 0.99, CK/CV (Ningqiang & DaG 055): 0.77, CK: 0.2, CR: 0.12 and CB: 0.1. CAIs are Poisson distributed and if only small areas (<1000 mm2) are studied, the data are probably not representative of the true CAI modal abundances, explaining their reported large scatter in a single chondrite group. Carbonaceous chondrites have excess bulk Al concentrations when compared to the CI-chondritic value. We find a correlation between this excess and CAI modal abundances and conclude that the excess Al was delivered by CAIs. The excess Al is only a minor fraction (usually ~10 rel%, but 25 rel% in case of CVs) of the bulk chondrite Al and cannot have contributed much 26Al to heat the chondrite parent body. Ordinary, enstatite, R- and K-chondrites have an Al deficit relative to CI chondrites and only very low CAI modal abundances, if any are present at all. Carbonaceous chondrites also had an initial Al deficit if the contribution of Al delivered by CAIs is subtracted. Therefore all chondrites probably lost a refractory rich high-T component. Only minor amounts of CAIs are present in the matrix or have been present in the chondrule precursor aggregates. Most CAI size distributions contain more than one size population, indicating that CAIs from within a single meteorite group had different origins.