From diluted magnetic semiconductors to self-organized nanocolumns of GeMn in Germanium

TL;DR

This paper explores the formation of self-organized Mn-rich nanocolumns in germanium via low-temperature Molecular Beam Epitaxy, demonstrating their ferromagnetic properties and potential for spintronic applications.

Contribution

It introduces a novel growth method for Mn-rich nanocolumns in germanium and characterizes their magnetic and transport properties, advancing the understanding of inhomogeneous magnetic semiconductors.

Findings

Nanocolumns are well organized and epitaxially aligned with germanium matrix.

Strong ferromagnetic interactions are confirmed by spectroscopy and magnetometry.

Magneto-transport features depend on the magnetic configuration of the nanocolumns.

Abstract

While achieving high Curie temperatures (above room temperature) in diluted magnetic semiconductors remains a challenge in the case of well controlled homogeneous alloys, several systems characterized by a strongly inhomogeneous incorporation of the magnetic component appear as promising. Incorporation of manganese into germanium drastically alters the growth conditions, and in certain conditions of low temperature Molecular Beam Epitaxy it leads to the formation of well organized nanocolumns of a Mn-rich material, with a crystalline structure in epitaxial relationship with the Mn-poor germanium matrix. A strong interaction between the Mn atoms in these nanocolums is demonstrated by x-ray absorption spectroscopy, giving rise to a ferromagnetic character as observed through magnetometry and x-ray magnetic circular dichroism. Most interesting, intense magneto-transport features are observed on the whole structure, which strongly depend on the magnetic configuration of the nanocolumns.