Theory of the Ordered Phase in A-site Antiferromagnetic Spinels

TL;DR

This paper develops a phenomenological Landau theory for the magnetic ordering in A-site antiferromagnetic spinels, explaining spin orientations, reorientations, and potential ferroelectricity, with insights supported by experiments on MnSc2S4.

Contribution

It introduces a comprehensive Landau theory capturing magnetic anisotropy, spin reorientation, and magnetically-induced ferroelectricity in A-site spinels, advancing understanding of their ordered states.

Findings

Predicts spin orientations in incommensurate spiral states

Describes spin reorientation under magnetic fields

Suggests ferroelectricity is a generic feature

Abstract

Insulating spinel materials, with the chemical formula $AB_2X_4$, behave as diamond lattice antiferromagnets when only the A-site atom is magnetic. Many exhibit classic signatures of frustration, induced not geometrically but by competing first and second neighbor exchange interactions. In this paper, we further develop a theory of the magnetism of these materials, focusing on the physics observable within the ordered state. We derive a phenomenological Landau theory that predicts the orientation of the spins within incommensurate spiral ordered states. It also describes how the spins reorient in a magnetic field, and how they may undergo a low temperature "lock-in" transition to a commensurate state. We discuss microscopic mechanisms for these magnetic anisotropy effects. The reduction of the ordered moment by quantum fluctuations is shown to be enhanced due to frustration. Our results are compared to experiments on MnSc_2S_4, the best characterized of such A-site spinels, and more general implications are discussed. One prediction is that magnetically-induced ferroelectricity is generic in these materials, and a detailed description of the relation of the electric polarization to the magnetism is given.