Diffusion in confined geometries

TL;DR

This paper reviews recent theoretical and numerical advances in understanding diffusive transport in confined geometries, highlighting entropic effects, anomalous diffusion, and particle interactions in micro- and nanoscale systems.

Contribution

It provides a comprehensive survey of new insights into stochastic transport in confined spaces, emphasizing entropic influences and anomalous diffusion phenomena.

Findings

Transport shows decreased nonlinear mobility with higher temperature.

Effective diffusion can exceed free diffusion due to entropic effects.

Sub-diffusion and resonance phenomena occur in narrow, modulated channels.

Abstract

Diffusive transport of particles or, more generally, small objects is a ubiquitous feature of physical and chemical reaction systems. In configurations containing confining walls or constrictions transport is controlled both by the fluctuation statistics of the jittering objects and the phase space available to their dynamics. Consequently, the study of transport at the macro- and nanoscales must address both Brownian motion and entropic effects. With this survey we report on recent advances in the theoretical and numerical investigation of stochastic transport occurring either in micro-sized geometries of varying cross section or in narrow channels wherein the diffusing particles are hindered from passing each other (single file diffusion). For particles undergoing biased diffusion in static suspension media enclosed by confining geometries, transport exhibits intriguing features such as (i) a decrease of nonlinear mobility with increasing temperature or, also, (ii) a broad excess peak of the effective diffusion above the free diffusion limit. These paradoxical aspects can be understood in terms of entropic contributions resulting from the restricted dynamics in phase space. If, in addition, the suspension medium is subjected to external, time-dependent forcing, rectification or segregation of the diffusing Brownian particles becomes possible. Likewise, the diffusion in very narrow, spatially modulated channels gets modified via contact particle-particle interactions, which induce anomalous sub-diffusion. The effective sub-diffusion constant for a driven single file also develops a resonance-like structure as a function of the confining coupling constant.