Slip and flow of hard-sphere colloidal glasses

TL;DR

This study investigates the flow behavior of concentrated hard-sphere colloidal glasses, revealing a transition from Herschel-Bulkley to Bingham slip response and providing a phenomenological model for slip and flow characteristics.

Contribution

It introduces a detailed analysis of slip and flow in colloidal glasses, including a phenomenological model and scaling laws for slip parameters.

Findings

Flow transitions from Herschel-Bulkley to Bingham slip response

Microstructure during slip observed via confocal microscopy

Slip parameters scale with particle size and concentration

Abstract

We study the flow of concentrated hard-sphere colloidal suspensions along smooth, non-stick walls using cone-plate rheometry and simultaneous confocal microscopy. In the glass regime, the global flow shows a transition from Herschel-Bulkley behavior at large shear rate to a characteristic Bingham slip response at small rates, absent for ergodic colloidal fluids. Imaging reveals both the `solid' microstructure during full slip and the local nature of the `slip to shear' transition. Both the local and global flow are described by a phenomenological model, and the associated Bingham slip parameters exhibit characteristic scaling with size and concentration of the hard spheres.