Quantum theory of ultracold atom-ion collisions

TL;DR

This paper develops an analytical quantum model for ultracold atom-ion collisions, focusing on Feshbach resonances in the 40Ca+ - Na system, and demonstrates the potential for precise interaction tuning with minimal charge exchange.

Contribution

It introduces a multichannel quantum defect formalism for atom-ion scattering and compares it with numerical calculations, providing system-independent insights.

Findings

Multiple Feshbach resonances at accessible magnetic fields enable tuning of interactions.

Charge exchange rates remain low even near resonances.

Results are applicable to charge-neutral ultracold systems.

Abstract

We study atom-ion scattering in the ultracold regime. To this aim, an analytical model based on the multichannel quantum defect formalism is developed and compared to close-coupled numerical calculations. We investigate the occurrence of magnetic Feshbach resonances focusing on the specific 40Ca+ - Na system. The presence of several resonances at experimentally accessible magnetic fields should allow the atom-ion interaction to be precisely tuned. A fully quantum-mechanical study of charge exchange processes shows that charge-exchange rates should remain small even in the presence of resonance effects. Most of our results can be cast in a system-independent form and are important for the realization of the charge-neutral ultracold systems.