The Influence of A-site Ionic Radii on the Magnetic Structure of Charge Ordered La0.5Ca0.5-xSrxMnO3 Manganites

TL;DR

This study investigates how the size of A-site ions affects the magnetic and structural properties of La0.5Ca0.5-xSrxMnO3 manganites, revealing a transition from charge-ordered antiferromagnetic to ferromagnetic states as ionic radii increase.

Contribution

It provides detailed insights into the correlation between A-site ionic radii and magnetic structures, including phase transitions and orbital ordering in La0.5Ca0.5-xSrxMnO3 compounds.

Findings

Charge order stable up to <rA> ~ 1.24A

Magnetic structure transitions from CE-type AFM to FM

Orbital ordering observed in samples with x ≤ 0.4

Abstract

The influence of the A-site ionic radii (<rA>) on the magnetic structure has been investigated in La0.5Ca0.5-xSrxMnO3 compounds (0 .GE. x .LE. 0.5) using neutron diffraction, magnetization, and resistivity techniques. All compounds in the composition range x .LE. 0.3 crystallize in the orthorhombic structure (Space Group Pnma). No further structural transition is observed as temperature is lowered below 300K. The compound x = 0.4, is a mixture of two orthorhombic phases crystallizing in Pnma and Fmmm space group. The x = 0.5 compound has a tetragonal structure in the space group, I4/mcm. The charge ordered (CO) state with CE-type antiferromagnetic order remains stable for x .LE. 0.3. Above x = 0.3, the CE-type antiferromagnetic state is suppressed. In x = 0.4 compound, A-type antiferromagnetic ordering is found at temperatures below 200K. Orbital ordering accompanying the spin ordering is found in all the samples with x .LE. 0.4. The system becomes ferromagnetic at x = 0.5 and no signature of orbital ordering is observed. As a function of <rA>, the charge ordered state is stable up to <rA> ~ 1.24A, and is suppressed thereafter. The magnetic structure undergoes a transformation from CE-type antiferromagnetic state to a ferromagnetic state with an intermediate A-type antiferromagnetic state.