Hybridization Effects in Ni-Mn based Shape Memory Alloys: XAFS Study

TL;DR

This study uses XAFS to investigate local atomic and electronic structure changes in Ni-Mn based shape memory alloys during phase transitions, revealing hybridization's role in structural transformation.

Contribution

It provides new experimental evidence on how hybridization influences phase transitions in Ni-Mn based Heusler alloys using XAFS analysis.

Findings

Identified local structural changes around metal ions during phase transition.

Demonstrated the role of hybridization in driving martensitic transformation.

Provided detailed atomic-level insights into alloy behavior.

Abstract

Martensitic and magnetic properties of ferromagnetic shape memory alloys are known to depend up on structural modulations and associated changes in the Fermi surface. These modulations although periodic and spanning over multiple unit cells, involve movement of atoms typically of the order of 0.01A. Therefore X-ray Absorption Fine Structure (XAFS) is an ideal tool to map both, local atomic movements and changes in density of states (DOS) due to changing hybridization as the system transforms from austenitic to martensitic phase. This paper presents a compilation of our XAFS studies on the Ni-Mn based shape memory alloys. A complete description of the changes in local structure around the constituent metal ions in the following alloy compositions: Ni2+xMn1-xGa, Ni2Mn1.4Sn0.6 and Ni2Mn1.4In0.6 in the austenitic and martensitic phases have been obtained. The results give the new experimental evidence for the crucial hybridization component that influences and leads to structural transition in these Ni-Mn based Heusler alloys.