Potassium ground state scattering parameters and Born-Oppenheimer potentials from molecular spectroscopy

TL;DR

This paper reports high-precision measurements of potassium molecule energy levels, deriving new ground state potentials and scattering parameters, and testing the Born-Oppenheimer approximation's validity in cold collision scenarios.

Contribution

It provides the first high-precision spectroscopic data for $^{39}$K$_2$, leading to improved ground state potentials and scattering lengths, and assesses the Born-Oppenheimer approximation at MHz accuracy.

Findings

Precise energy level measurements with MHz uncertainty.

New ground state potentials fitted from spectroscopic and collision data.

Validation of the Born-Oppenheimer approximation at high precision.

Abstract

We present precision measurements with MHz uncertainty of the energy gap between asymptotic and well bound levels in the electronic ground state X $^1\Sigma_{\mathrm{g}}^+$ of the $^{39}$K$_2$ molecule. The molecules are prepared in a highly collimated particle beam and are interrogated in a $\Lambda$-type excitation scheme of optical transitions to long range levels close to the asymptote of the ground state, using the electronically excited state A $^1\Sigma^+_{\rm u}$ as intermediate one. The transition frequencies are measured either by comparison with I$_2$ lines or by absolute measurements using a fs-frequency comb. The determined level energies were used together with Feshbach resonances from cold collisions of $^{39}$K and $^{40}$K reported from other authors to fit new ground state potentials. Precise scattering lengths are determined and tests of the validity of the Born-Oppenheimer approximation for the description of cold collisions at this level of precision are performed.