Structural and 121Sb M\"ossbauer Spectroscopic Investigations of the Antimonide Oxides REMnSbO (RE = La, Ce, Pr, Nd, Sm, Gd, Tb) and REZnSbO (RE = La, Ce, Pr)
Inga Schellenberg, Tom Nilges, Rainer P\"ottgen
TL;DR
This study synthesizes and characterizes a series of antimonide oxides REMnSbO and REZnSbO using X-ray and 121Sb Mössbauer spectroscopy, revealing detailed structural and electronic insights into these compounds.
Contribution
It provides new synthesis routes and detailed spectroscopic analysis of REMnSbO and REZnSbO compounds, expanding understanding of their structural and electronic properties.
Findings
Successful synthesis of REMnSbO and REZnSbO compounds.
Detailed 121Sb Mössbauer spectra obtained and analyzed.
Structural data from single crystal X-ray diffraction provided.
Abstract
The quaternary antimonide oxides REMnSbO (RE = La, Ce, Pr, Nd, Sm, Gd, Tb) and REZnSbO (RE = La, Ce, Pr) were synthesized from the RESb monoantimonides and MnO, respectively ZnO. We report on single crystal X-ray data and a detailed 121Sb M\"ossbauer spectroscopic investigation.
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Taxonomy
TopicsInorganic Chemistry and Materials · Rare-earth and actinide compounds · Nuclear materials and radiation effects