Fluid-bicontinuous gels stabilized by interfacial colloids: low and high molecular weight fluids

TL;DR

This paper reviews the development of colloid-stabilized bicontinuous gels with liquid domains, created by arresting phase separation and trapping colloids at interfaces, applicable to low and high molecular weight fluids.

Contribution

It compares the formation of bicontinuous structures in low and high molecular weight fluids, highlighting the role of colloids and phase separation in stabilizing these complex materials.

Findings

Bicontinuous structures can be stabilized by colloids during phase separation.

Similar structures are achievable in polymer blends with nanoparticles or clay platelets.

Low and high molecular weight systems offer insights into structure formation and stabilization.

Abstract

Carefully tuned composite materials can have properties wholly unlike their separate constituents. We review the development of one example: colloid-stabilized emulsions with bicontinuous liquid domains. These non-equilibrium structures resemble the sponge mesophase of surfactants; however, in the colloid-stabilized case the interface separating the liquid domains is itself semi-solid. The arrangement of domains is created by arresting liquid-liquid phase separation via spinodal decomposition. Dispersed colloids exhibiting partial wettability become trapped on the newly created interface and jam together as the domains coarsen. Similar structures have been created in polymer blends stabilized using either interfacial nanoparticles or clay platelets. Here it has been possible to create the domain arrangement either by phase separation or by direct mixing of the melt. The low molecular-weight liquid and polymer based structures have been developed independently and much can be learnt by comparing the two.