Absence of Hole Confinement in Transition Metal Oxides with Orbital Degeneracy
M. Daghofer, K. Wohlfeld, A. M. Oles, E. Arrigoni, P. Horsch

TL;DR
This paper explores hole movement in a 2D Hubbard model with t_2g electrons, revealing a unique quasi-1D coherent motion driven by three-site terms, and shows orbital degeneracy alone doesn't cause hole self-localization.
Contribution
It demonstrates a novel mechanism for hole motion in orbital models that differs from traditional quantum fluctuation-based explanations.
Findings
Quasi-1D coherent hole motion arises despite Ising-like superexchange.
Orbital degeneracy alone does not induce hole self-localization.
Effective three-site terms enable unique hole propagation mechanisms.
Abstract
We investigate the spectral properties of a hole moving in a two-dimensional Hubbard model for strongly correlated t_2g electrons. Although superexchange interactions are Ising-like, a quasi-one-dimensional coherent hole motion arises due to effective three-site terms. This mechanism is fundamentally different from the hole motion via quantum fluctuations in the conventional spin model with SU(2) symmetry. The orbital model describes also propagation of a hole in some e_g compounds, and we argue that orbital degeneracy alone does not lead to hole self-localization.
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Taxonomy
TopicsCatalytic Processes in Materials Science · Catalysis and Oxidation Reactions · Magnetic and transport properties of perovskites and related materials
