Micellar Crystals in Solution from Molecular Dynamics Simulations

TL;DR

This study uses molecular dynamics simulations to explore the formation, dynamics, and equilibrium properties of micellar crystals in triblock polymers, revealing insights into their lattice structures and transition behaviors.

Contribution

It provides new understanding of micellar crystal formation and dynamics, highlighting the role of polymer transfer and identifying conditions favoring different lattice structures.

Findings

Equilibration occurs via polymer transfer between micelles.

bcc lattices are favored near the melting transition.

fcc lattices appear at lower temperatures and with short hydrophilic blocks.

Abstract

Polymers with both soluble and insoluble blocks typically self-assemble into micelles, aggregates of a finite number of polymers where the soluble blocks shield the insoluble ones from contact with the solvent. Upon increasing concentration, these micelles often form gels that exhibit crystalline order in many systems. In this paper, we present a study of both the dynamics and the equilibrium properties of micellar crystals of triblock polymers using molecular dynamics simulations. Our results show that equilibration of single micelle degrees of freedom and crystal formation occurs by polymer transfer between micelles, a process that is described by transition state theory. Near the disorder (or melting) transition, bcc lattices are favored for all triblocks studied. Lattices with fcc ordering are also found, but only at lower kinetic temperatures and for triblocks with short hydrophilic blocks. Our results lead to a number of theoretical considerations and suggest a range of implications to experimental systems with a particular emphasis on Pluronic polymers.