Magnetic and orbital ordering in the spinel MnV2O4

TL;DR

This study uses neutron scattering to explore magnetic and orbital ordering in MnV2O4, revealing two magnetic transitions, a tetragonal distortion, and a noncollinear magnetic structure linked to V orbital ordering.

Contribution

First detailed neutron scattering analysis of magnetic and orbital ordering in MnV2O4, identifying two magnetic transitions and the role of V orbital angular momentum.

Findings

Two magnetic transitions to ferrimagnetic states

Identification of a tetragonal distortion at low temperature

Discovery of a noncollinear magnetic structure with an anisotropy gap

Abstract

Neutron inelastic scattering and diffraction techniques have been used to study the MnV2O4 spinel system. Our measurements show the existence of two transitions to long-range ordered ferrimagnetic states; the first collinear and the second noncollinear. The lower temperature transition, characterized by development of antiferromagnetic components in the basal plane, is accompanied by a tetragonal distortion and the appearance of a gap in the magnetic excitation spectrum. The low-temperature noncollinear magnetic structure has been definitively resolved. Taken together, the crystal and magnetic structures indicate a staggered ordering of the V d orbitals. The anisotropy gap is a consequence of unquenched V orbital angular momentum.