Interaction effects in mixed-valent Kondo insulators

TL;DR

This paper presents a theoretical study of mixed-valent Kondo insulators using a local moment approach, revealing novel spectral and transport features that align well with experimental observations in specific compounds.

Contribution

It introduces a new theoretical framework for mixed-valent Kondo insulators that explains experimental features outside previous models' scope.

Findings

Identification of a shoulder-like feature in optical conductivity.

Good agreement between theory and experiments on CeOs4Sb12.

Explanation of spectral features unique to mixed-valent systems.

Abstract

We study theoretically the class of mixed-valent Kondo insulators, employing a recently developed local moment approach to heavy Fermion systems using the asymmetric periodic Anderson model (PAM). Novel features in spectra and transport, observable experimentally but lying outside the scope of the symmetric PAM or the Kondo lattice model, emerge naturally within the present theory. We argue in particular that a shoulder-like feature in the optical conductivity, that is distinct from the usual mid-infrared or direct gap peak and has been observed experimentally in mixed-valent compounds such as CeOs4Sb12 and YbAl3, is of intrinsic origin. Detailed comparison is made between the resultant theory and transport/optical experiments on the filled-skutterudite compound CeOs4Sb12, and good agreement is obtained.