Growth, Structure and Properties of BiFeO3-BiCrO3 Films obtained by Dual Cross Beam PLD

TL;DR

This paper reports the successful synthesis and characterization of epitaxial BiFeO3-BiCrO3 films with multiferroic properties, revealing room-temperature magnetic ordering influenced by cation arrangement, using dual cross beam pulsed laser deposition.

Contribution

It introduces a novel dual cross beam PLD method to produce epitaxial BiFeO3-BiCrO3 films with controlled structure and multiferroic properties, highlighting the role of cation ordering.

Findings

Room-temperature magnetic ordering observed in BFCO films.

Cr3+ and Fe3+ ions are in 3+ oxidation state.

Magnetic behavior depends on cation arrangement.

Abstract

The properties of epitaxial Bi2FeCrO6 thin films, recently synthesized by pulsed laser deposition, have partially confirmed the theoretical predictions (i.e. a magnetic moment of 2 muB per formula unit and a polarization of ~80 microC/cm2 at 0K). The existence of magnetic ordering at room temperature for this material is an unexpected but very promising result that needs to be further investigated. Since magnetism is assumed to arise from the exchange interaction between the Fe and Cr cations, the magnetic behaviour is strongly dependent on both their ordering and the distance between them. We present here the successful synthesis of epitaxial Bi2FexCryO6 (BFCO x/y) films grown on SrTiO3 substrates using dual crossed beam pulsed laser deposition. The crystal structure of the films has different types of (111)-oriented superstructures depending on the deposition conditions. The multiferroic character of BFCO (x/y) films is proven by the presence of both ferroelectric and magnetic hysteresis at room temperature. The oxidation state of Fe and Cr ions in the films is shown to be 3+ only and the difference in macroscopic magnetization with Fe/Cr ratio composition could only be due to ordering of the Cr3+ and Fe3+ cations therefore to the modification of the exchange interaction between them.