Characterization of the Core-Shell Nanoparticles Formed as Soluble Hydrogen-Bonding Interpolymer Complexes at low pH

TL;DR

This study investigates the formation and structure of core-shell nanoparticles resulting from hydrogen-bonding interpolymer complexes between PAA and a graft copolymer at low pH, revealing stable insoluble cores with a corona.

Contribution

It provides detailed characterization of the core-shell structure and stability of these nanoparticles using multiple scattering and microscopy techniques, highlighting their potential for applications requiring stable colloidal systems.

Findings

Core-shell nanoparticles form with a stable insoluble PAA/PDMAM core.

Complexes create a transient gel network in semidilute solutions.

Particles collapse and flatten upon substrate deposition.

Abstract

The formation of soluble hydrogen-bonding interpolymer complexes between poly(acrylic acid) (PAA) and poly(acrylic acid-co-2-acrylamido-2-methyl-1-propane sulfonic acid)-graft-poly(N, N dimethylacrylamide) (P(AA-co-AMPSA)-g-PDMAM) at pH = 2.0 was studied. A viscometric study showed that in semidilute solution a physical gel is formed, due to the interconnection of the anionic P(AA-co-AMPSA) backbone of the graft copolymer, in a transient network, by means of the complexes formed between the PDMAM side chains of the graft copolymer and PAA. Dynamic and static light scattering measurements, in conjunction with small angle neutron scattering measurements, suggest the formation of core-shell colloidal nanoparticles in dilute solution, comprised by an insoluble PAA/PDMAM core surrounded by an anionic P(AA-co-AMPSA) corona. Even if larger clusters are formed in semidilute solution, the size of the insoluble core remains practically stable. Atomic force microscopy performed under ambient conditions, reveal that the particles collapse and flatten upon deposition on a substrate, with dimensions close to the ones of the dry hydrophobic core.