Shape resonances in modified effective range theory for electron-molecule collisions

TL;DR

This paper presents a simplified model based on modified effective-range theory to predict shape resonances in electron-molecule collisions, successfully matching experimental data for N₂ and CO₂ within a specific energy range.

Contribution

The authors develop a novel, analytically solvable model using modified effective-range expansion to accurately predict shape resonances in electron-molecule scattering.

Findings

Model predicts shape resonances slightly higher than experimental values.

Agreement improves when adjusting resonance positions in partial waves.

Quadrupole potential effects are significant for CO₂ but negligible for N₂.

Abstract

We develop a simple model of shape resonances in electron-molecule collisions that is based on the modified effective-range expansion and analytical solutions of the Schrodinger equation for the long-range part of the interaction potential. We apply our model to electron scattering on N$_2$ and CO$_2$. The parameters of the effective-range expansion (i.e. the scattering length and the effective range) are determined from experimental, integral elastic cross sections in the 0.1 - 1.0 eV energy range. For both molecular targets our treatment predicts shape resonances that appear slightly higher than experimentally known resonances in total cross sections. Agreement with the experiment can be improved by assuming the position of the resonance in a given partial wave. Influence of quadrupole potential on resonances is also discussed: it can be disregarded for N$_2$ but gets significant for CO$_2$. In conclusion, our model developed within the effective range formalism reproduces well both the very low-energy behavior of the integral cross section as well as the presence of resonances in the few eV range.