Synthesis, characterization, and application of carbon cubes

TL;DR

This study develops a method for synthesizing multiwall carbon nanotubes with specific properties and explores their effectiveness in removing lead ions from environmental samples.

Contribution

It introduces an optimized synthesis process for multiwall CNTs and demonstrates their application in lead ion adsorption for environmental remediation.

Findings

Successfully synthesized well-graphited MWCNTs with diameters of 30-100 nm.

Characterized MWCNTs using TEM, EDS, XRPD, XANES, and EXAFS techniques.

Demonstrated effective removal of lead ions using synthesized MWCNTs.

Abstract

Carbon nanotubes (CNTs) have attracted increasing attention because of their unique structural, mechanical, and electronic properties. Surface chemistry modifications are also useful and critical to manipulate the adsorptive properties of CNTs and develop their potential of environmental application. Therefore, the main objectives of this study were to investigate the optimal synthesis methods or characteristics identification of multiwall CNTs (MWCNTs) and the environmental application of lead ions adsorptive removal by CNTs. Experimentally, the MWCNTs of well-graphited walls were obtained with reductive potassium metals of catalytic hexachlorobenzene-thermal routes in the presence of Co/Ni catalyst precursors at 503-623 K for 8- 12 hr. The diameters of MWCNTs ranged of 30-100 nm by TEM microphotos. In addition, fine structures or surface chemical modification of MWCNTs or Co/Ni precursors were further identified by EDS, XRPD, X-ray absorption near edge structural (XANES) or extended Xray absorption fine structural (EXAFS) spectroscopy. 1.