Growth dynamics of vertically aligned single-walled carbon nanotubes from in situ measurements

TL;DR

This study uses in situ optical absorbance to analyze the growth dynamics of vertically aligned single-walled carbon nanotubes, revealing exponential decay in growth rate, optimal conditions, and a new method for determining burning temperature.

Contribution

It introduces a novel in situ measurement approach to study VA-SWCNT growth and identifies key growth parameters and reaction kinetics.

Findings

Growth rate decays exponentially with a 15-minute effective growth time.

Optimal pressure for maximum growth depends on temperature.

A new method for determining burning temperature via in situ absorbance and oxidation.

Abstract

An in situ optical absorbance measurement was used to study the growth dynamics of vertically aligned single-walled carbon nanotubes (VA-SWCNTs) synthesized by chemical vapor deposition of ethanol. The growth rate of the VA-SWCNT film was found to decay exponentially from an initial maximum, resulting in an effective growth time of approximately 15 minutes. Investigation of various growth conditions revealed an optimum pressure at which growth is maximized, and this pressure depends on the growth temperature. Below this optimum pressure the synthesis reaction is first-order, and the rate-limiting step is the arrival of ethanol at the catalyst. We also present a novel method for determining the burning temperature of low-mass materials, which combines the in situ absorbance measurement with controlled oxidation.