On the conundrum of deriving exact solutions from approximate master equations
Roland Doll, David Zueco, Martijn Wubs, Sigmund Kohler, Peter, Hanggi

TL;DR
This paper derives the exact time-evolution for quantum systems under phase-noise and shows that a second-order perturbative master equation can yield exact results for Gaussian initial bath states, clarifying its relation to the Bloch-Redfield approach.
Contribution
It demonstrates the conditions under which a second-order time-local master equation provides exact solutions for quantum systems with phase-noise, linking it to Gaussian bath states and the Bloch-Redfield method.
Findings
Exact evolution derived for phase-noise systems.
Second-order master equation matches exact results for Gaussian baths.
Clarifies the relation to Bloch-Redfield approach.
Abstract
We derive the exact time-evolution for a general quantum system under the influence of pure phase-noise and demonstrate that for a Gaussian initial state of the bath, the exact result can be obtained also within a perturbative time-local master equation approach already in second order of the system-bath coupling strength. We reveal that this equivalence holds if the initial state of the bath can be mapped to a Gaussian phase-space distribution function. Moreover, we discuss the relation to the standard Bloch-Redfield approach.
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Taxonomy
TopicsSpectroscopy and Quantum Chemical Studies · Quantum Information and Cryptography · Advanced Thermodynamics and Statistical Mechanics
