A perturbation theory for large deviation functionals in fluctuating hydrodynamics

TL;DR

This paper develops a perturbation approach to analyze large deviation functionals in fluctuating hydrodynamics, linking deviations to excess entropy production during fluctuation processes.

Contribution

It introduces a perturbation method for solving large deviation functionals in stochastic diffusion equations, connecting deviations to entropy production.

Findings

Derived the lowest order expression for deviations from local equilibrium.

Linked large deviation functional to excess entropy production.

Provided a systematic perturbation framework for fluctuation analysis.

Abstract

We study a large deviation functional of density fluctuation by analyzing stochastic non-linear diffusion equations driven by the difference between the densities fixed at the boundaries. By using a fundamental equality that yields the fluctuation theorem, we first relate the large deviation functional with a minimization problem. We then develop a perturbation method for solving the problem. In particular, by performing an expansion with respect to the average current, we derive the lowest order expression for the deviation from the local equilibrium part. This expression implies that the deviation is written as the space-time integration of the excess entropy production rate during the most probable process of generating the fluctuation that corresponds to the argument of the large deviation functional.