Mapping electron delocalization by charge transport spectroscopy in an artificial molecule

TL;DR

This paper demonstrates how charge transport spectroscopy can map electron delocalization in a carbon nanotube artificial molecule, revealing quantum state hybridization and electron superposition effects.

Contribution

It introduces an experimental method to measure the superposition of quantum states in a carbon nanotube quantum dot system using electrical transport.

Findings

Electron delocalization is observed through transport measurements.

Hybridization of quantum states is tunable via gate voltages.

This work advances quantum state engineering in nanotube systems.

Abstract

In this letter we present an experimental realization of the quantum mechanics textbook example of two interacting electronic quantum states that hybridize forming a molecular state. In our particular realization, the quantum states themselves are fabricated as quantum dots in a molecule, a carbon nanotube. For sufficient quantum-mechanical interaction (tunnel coupling) between the two quantum states, the molecular wavefunction is a superposition of the two isolated (dot) wavefunctions. As a result, the electron becomes delocalized and a covalent bond forms. In this work, we show that electrical transport can be used as a sensitive probe to measure the relative weight of the two components in the superposition state as a function of the gate-voltages. For the field of carbon nanotube double quantum dots, the findings represent an additional step towards the engineering of quantum states.